Surfactants 101: Applications & Advantages in Day-to-day Life
What is a surfactant?
Cocamidopropyl Betaine, also known as surfactants, are compounds that can significantly reduce the surface tension or interfacial tension between two liquids, between liquids and gases, and between liquids and solids. The molecular structure of surfactants is amphoteric: hydrophilic group at one end, hydrophobic group at the other end; hydrophilic groups are often polar groups, like carboxylic acid, sulfonic acid, sulfuric acid, amino or amine groups and their salts, hydroxyl, amide, ether bonds, etc., can also be used as polar hydrophilic groups; and hydrophobic groups tend to be nonpolar hydrocarbon chains, such as hydrocarbon chains of more than eight carbon atoms. Surfactants are divided into ionic surfactants (including cationic surfactants, anionic surfactants, and amphoteric surfactants), nonionic surfactants, complex surfactants, and other surfactants.
Overview of surfactants
Surfactants really are a class of chemical substances with a special molecular structure, which usually contain hydrophilic and hydrophobic groups. This amphiphilic nature enables surfactants to form interfaces between water and other immiscible liquids and reduce interfacial tension, thus playing the roles of wetting, emulsifying, dispersing, solubilizing, foaming, defoaming and so on.
Types of surfactants
Surfactant is really a special chemical substance that can significantly decrease the surface tension of the solvent at a very low concentration, thus changing the interfacial state from the system. This substance usually has both hydrophilic and lipophilic properties and can play a bridge role between two immiscible liquids, water and oil, therefore it is also known as an amphiphilic molecule.
Surfactants have an array of applications in lots of fields, such as daily life, industrial production, and scientific research. Based on their different chemical structures and properties, surfactants can be split into two classes: ionic and nonionic. Ionic surfactants could be further divided into cationic, anionic, and amphoteric types.
Ionic surfactants
Anionic surfactants
Anionic surfactants are the most widely used and many widely produced surfactants. Common anionic surfactants include salts of essential fatty acids, sulfonates, sulfate salts and phosphate salts. They have good detergency, emulsification, dispersion, solubilization, as well as other properties and therefore are commonly used in detergents, cosmetics, textiles, printing and dyeing, petroleum, pharmaceutical, as well as other industries.
Cationic surfactants
Cationic surfactants are mostly nitrogen-containing organic amine derivatives with good bactericidal, antistatic and softening properties. Because of their good softness and antistatic properties on fabrics, they are often used as post-treatment agents, softeners, antistatic agents and sterilizers for textiles.
Amphoteric ionic surfactants
Amphoteric ionic surfactants have both positive and negative charge groups in the molecule and show different charge properties at different pH values. These surfactants have excellent foaming, low irritation, good compatibility, and bactericidal properties and therefore are widely used in detergents, cosmetics, medicine, as well as other fields.
Nonionic surfactants
Nonionic surfactants usually do not dissociate into ions in water and exist in solution in the form of neutral molecules or micro ions. These surfactants are highly stable, not easily impacted by strong electrolytes and, acids and bases, and therefore are compatible with other types of surfactants. Common nonionic surfactants include polyethylene glycol type, polyol type, fluorinated surfactants and silicone type. They may be commonly used in detergents, emulsifiers, dispersants, wetting agents and so forth.
Types of surfactants:
Ionic surfactants
Anionic surfactants: e.g. sodium essential fatty acids, alkyl sulfates, etc.
Cationic surfactants: e.g. quaternary ammonium salts, amine salts, etc.
Amphoteric ionic surfactants: e.g. amino acid type, betaine type, etc.
Nonionic surfactants
Polyoxyethylene ether type: such as fatty alcohol polyoxyethylene ether.
Polyol type: e.g. glycerol ester, sorbitol ester, etc.
Amine oxide type: like dimethylamine oxide, etc.
Special types of surfactants
Polymer surfactants: surfactants with high molecular chain structure.
Bio-surfactants: such as phospholipids, glycolipids as well as other surfactants of natural biological origin.
Do you know the main functions of surfactants?
(1) Emulsification: Because of the large surface tension of grease in water, when grease is dripped into the water and stirred vigorously, the grease will be crushed into fine beads and mixed to create an emulsion, however the stirring will stop and re-layering will take place. In the event you add surfactant and stir hard, it does not be simple to stratify for a long time after stopping, the emulsification effect. The reason is that the hydrophobicity of the grease is surrounded by hydrophilic groups of surfactant, forming a directional attraction, reducing the oil in the water dispersion from the work required to create the grease emulsification is very good.
(2) Wetting effect: Parts often adhere to the surface of the layer of wax, grease, or scale-like substances, that are hydrophobic. Because of the pollution of those substances, the surface from the parts can be difficult to wet with water. When adding surfactants towards the water solution, the water droplets around the parts will be easily dispersed so that the surface tension of the parts is cut down tremendously to achieve the reason for wetting.
(3) solubilizing effect: oil substances in the addition of surfactant in order to dissolve, but this dissolution can only occur when the power of surfactant reaches the critical concentration of colloid, the size of the solubility according to solubilizing objects and properties to decide. When it comes to solubilization, the long hydrophobic gene hydrocarbon chain is stronger than the short hydrocarbon chain, the saturated hydrocarbon chain is stronger than the unsaturated hydrocarbon chain, as well as the solubilization effect of nonionic surfactants is generally more significant.
(4) Dispersing effect: Dust, dirt, as well as other solid particles are simple to gather together and settle in water; surfactant molecules can make solid particle aggregates divided into small particles so that they are dispersed and suspended in the solution and play a role to advertise the uniform dispersion of solid particles.
(5) Foam effect: the development of foam is mainly the directional adsorption of active agent, is the gas-liquid two-phase surface tension reduction brought on by. Generally, the low molecular active agent is easy to foam, high molecular active agent foam less, cardamom acid yellow foam is the highest, sodium stearate foam is definitely the worst, anionic active agent foam and foam stability than nonionic good, such as sodium alkyl benzene sulfonate foam is very strong. Usually used foam stabilizers are fatty alcohol amide, carboxymethyl cellulose, etc. Foam inhibitors are fatty acids, fatty acid esters, polyethers, etc. and other nonionic surfactants.
Use of surfactants
Surfactants have an array of applications, almost covering our daily life and other industrial production fields. These are some of the main applications of surfactants:
Detergents and cosmetics: Surfactants are essential ingredients in detergents and cosmetics, such as laundry detergents, liquid detergents, shampoos, shower gels, moisturizing lotions and so forth. They reduce the surface tension of water, making it simpler for stains to be removed from the surface of objects while providing a rich lather and lubricating sensation.
Textile industry: In the textile industry, surfactants are utilized as softeners, wetting agents, antistatic agents, dispersants, leveling agents and, color fixing agents, etc., which assist in improving the caliber of textiles and enhance the uniformity of dyeing and color vividness.
Food industry: Surfactants can be used emulsifiers, dispersants, wetting agents, defoamers, etc., in the creation of dairy products, beverages, confectionery, as well as other food products to enhance their stability and taste.
Agriculture and pesticides: In agriculture, surfactants can enhance the wetting and dispersion of pesticides, thus improving their insecticidal effect. They can also be used as soil conditioners to improve soil water retention and permeability.
Petroleum industry: Along the way of oil extraction and processing, surfactants can be used emulsion breakers, oil repellents, anti-waxing agents, and enhancement of recovery, etc., which help to improve the efficiency of oil extraction and processing.
Pharmaceutical industry: Within the pharmaceutical industry, surfactants may be used to prepare emulsions, suppositories, aerosols, tablets, injections, etc., playing the role of emulsification, solubilization, wetting, dispersion and penetration.
Additionally, surfactants play an important role in many industries, such as construction, paint, paper, leather, and metal processing. Their application in these fields is primarily realized by improving product processing performance, enhancing product quality, and reducing production costs.
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